Let's see what we have. A Schläfli symbol with length n is for a (n+1)-D polytope, or else for a n-D space tiling. I'll also consider only integer values of the symbols' values, and integer values >= 3. A value of 2 is a degenerate case. A polygon with it reduces to a line segment.
Length 0
s() = 1 -- line segments.
Length 1
The regular polygons, and one can easily show that s(p) = sin(pi/p)
One gets a line tiling as an infinite chain of line segments: p -> infinity.
The ones that can be continued are
s(3) = sqrt(3)/2 -- triangle (3-side)
s(4) = 1/sqrt(2) -- square (4-side)
s(5) = (1/4)*sqrt(10-2*sqrt(5)) -- pentagon (5-side)
s(6) = 1/2 -- hexagon (6-side)
Length 2
s(33) = sqrt(2/3) -- tetrahedron (4-face)
s(43) = 1/sqrt(3) -- cube (6-face)
s(53) = (sqrt(5)-1)/(2*sqrt(3)) -- dodecahedron (12-face)
s(63) = 0 -- hexagonal plane tiling
s(34) = 1/sqrt(2) -- octahedron (8-face)
s(44) = 0 -- square plane tiling
s(35) = sqrt(10-2*sqrt(5))/(2*sqrt(5)) -- icosahedron (20-face)
s(36) = 0 -- triangular plane tiling
So we get the 5 Platonic solids and 3 plane tilings
Length 3
s(333) = sqrt(5)/(2*sqrt(2)) -- simplex (5-cell)
s(433) = 1/2 -- tesseract or hypercube (8-cell)
s(533) = (3 - sqrt(5))/(4*sqrt(2)) -- 120-cell
s(343) = 1/2 -- 24-cell (halfway between an 8-cell and a 16-cell)
s(334) = 1/sqrt(2) -- cross-polytope (16-cell)
s(434) = 0 -- cubic space tiling
s(335) = (5-sqrt(5)/4 -- 600-cell
Length 4
s(3333) = sqrt(3/5) -- simplex
s(4333) = 1/sqrt(5) -- hypercube
s(3433) = 0 -- 24-cell space tiling
s(3343) = 0 -- 16-cell space-tiling
s(3334) = 1/sqrt(2) -- cross-polytope
s(4334) = 0 -- 8-cell (tesseract) space tiling
Length 5
s(33333) = (1/2)*sqrt(7/3) -- simplex
s(43333) = 1/sqrt(6) -- hypercube
s(33334) = 1/sqrt(2) -- cross-polytope
s(43334) = 0 -- hypercube space tiling
Length 6
s(333333) = 2/sqrt(7) -- simplex
s(433333) = 1/sqrt(7) -- hypercube
s(333334) = 1/sqrt(2) -- cross-polytope
s(433334) = 0 -- hypercube space tiling
Families
It ought to be evident that the polytopes settle down into a few families. In fact, these families are infinite. Their Schläfli symbols:
s(33...33) = sqrt((n+1)/(2n)) -- n-D simplex: triangle, tetrahedron, ...
s(43...33) = 1/sqrt
-- n-D hypercube: square, cube, tesseract, ...
s(33...34) = 1/sqrt(2) -- n-D cross-polytope: square, octahedron, ...
s(43...34) = 0 -- hypercube space tiling
The extra ones are as follows:
2D: polygons with at least 5 sides, and two plane tilings, the triangular and hexagonal plane ones
3D: the regular dodecahedron and icosahedron
4D: the 24-cell, 120-cell, and 600-cell, and two space tilings, for the 16-cell and the 24-cell