Methane's 3.31-mcm spectral line is well above the room-temperature blackbody peak of 10 mcm in energy. In any case, the NYT videos show plenty of detail, showing that it isn't mostly thermal emissions.
GCP - Carbon Budget - Visualizations:
A Brief History of CO2 Emissions – ᴜᴄʟᴀʙ - video showing that history. It all started in the UK then spread to elsewhere in the world. Shows big emitters as pillars on the globe.
The Great Decoupling - economic growth and carbon-emission growth, and how they are starting to decouple. Meaning the dawn of our second age of renewable energy.
Top 20 Country Carbon Dioxide (CO2) Emission History (1960-2017) - YouTube - the US was the world champion for most of that time. Around 1970, China beat Japan for 2nd place, and both nations beat the UK around then.
China beat the US in 2006, with Russia next -- and far behind. It was a bit bigger than Japan and India.
India beat Russia around 2009, and by 2017, China was twice the US, and the US twice India.
Countries with Largest CO2 emissions 1850-2017 - YouTube
The UK was the initial champion, easily beating every other nation combined.
After being neck and neck with France and Germany, the US surged ahead, beating the UK in 1888, with Germany at half it and France at half Germany.
By 1902, the US was at twice as much as the UK, Germany was a little behind the UK, and France about 1/3 as much.
By 1914, the US was at 3 times as much as the UK and Germany separately, and the UK was over 4 times as much as France and Russia separately.
There was a big decline in total output during the Great Depression, around 1933, then recovery. By 1939, Germany was a bit more than 1/3 of the US, and the UK and the USSR about 2/3 of Germany separately. By 1948, the USSR was the second largest at 1/5 the US, with the UK a little bit behind.
By 1957, when Sputnik 1 was launched, the USSR was about 1/3 the US and nearly twice the UK and W Germany separately. By 1973, the USSR was about 2/3 the US and 3 times China and Japan separately. The next in line were W Germany, the UK, and France.
The USSR broke up in 1991, and it was at 3/4 the US's emissions, China was at 1/2 the US, and Japan 1/5 the US.
By 2005, China had caught up with the US, and with Russia a bit more than 1/4, and Japan and India each at about 1/5. The next one was Germany at 1/6.