lpetrich
Contributor
How does it work?
CO2 + (x/2+2)*H2 -> (CHx) + 2H2O
Without linking two carbon atoms together, one would get this sequence:
CO2 + H2
HCOOH (formic acid) + H2 - H2O
CH2O (formaldehyde) + H2
CH3OH (methanol) + H2 - H2O
CH4 (methane)
Doing carbon-carbon bonding expands the range enormously, since one won't stop at two.
Olefin? Also called an alkene, it's a hydrocarbon with at least one double bond. That's useful for making some plastics, like polyethylene, polypropylene, and polystyrene, since they polymerize at their double bonds.
This is essentially the Fischer–Tropsch processThe key to the remarkable increase in reactivity is that layer of porous plastic on the ruthenium, explained lead student author Chengshuang Zhou, a doctoral candidate in Cargnello’s lab, who conducted the search and experimentation needed to refine the new coating. An uncoated catalyst works just fine, he said, but only produces methane, the shortest chain hydrocarbon, which has just a single atom of carbon bonded to four hydrogens. It’s not really a chain at all.
“An uncoated catalyst gets covered in too much hydrogen on its surface, limiting the ability of carbon to find other carbons to bond with,” Zhou said. “The porous polymer controls the carbon-to-hydrogen ratio and allows us to create longer carbon chains from the same reactions. This particular, crucial interaction was demonstrated using synchrotron techniques at SLAC National Laboratory in collaboration with the team of Dr. Simon Bare, who leads Co-Access there.”
While long-chain hydrocarbons are an innovative use of captured carbon, they are not perfect, Cargnello acknowledges. He is also working on other catalysts and similar processes that turn carbon dioxide into valuable industrial chemicals, like olefins used to make plastics, methanol and the holy grail, ethanol, all of which can sequester carbon without returning carbon dioxide to the skies.
“If we can make olefins from CO2 to make plastics,” Cargnello noted, “we have sequestered it into a long-term storable solid. That would be a big deal.”
CO2 + (x/2+2)*H2 -> (CHx) + 2H2O
Without linking two carbon atoms together, one would get this sequence:
CO2 + H2
HCOOH (formic acid) + H2 - H2O
CH2O (formaldehyde) + H2
CH3OH (methanol) + H2 - H2O
CH4 (methane)
Doing carbon-carbon bonding expands the range enormously, since one won't stop at two.
Olefin? Also called an alkene, it's a hydrocarbon with at least one double bond. That's useful for making some plastics, like polyethylene, polypropylene, and polystyrene, since they polymerize at their double bonds.